Untangling complex syste.., p.75

Untangling Complex Systems, page 75

 

Untangling Complex Systems
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  derives the that thermal gradients in the experiments 1 and 2, i.e., (Δ T) and (Δ

  , were

  1

  T)2

  0 0019

  .

  K < ( T

  ∆ ) < ( T

  ∆ ) < 0 0227

  .

  K. Finally, the height of the solution decreased 0.2 cm

  1

  2

  in 2200 s. Therefore, the power absorbed by the solution was about 0.036 J s−1.

  It is possible to experience the “butterfly effect” also by following the instructions of

  list B. The spectral evolution for the photochromic SpO under irradiation at 360 nm is

  reported in Figure 10.41. Initially, the solution in uncolored. Upon UV, a band centered

  at 612 nm forms and the solution becomes colored. The absorbance of the spectral

  band into the visible region grows until we reach the photo-stationary state. Then, it

  oscillates due to the convective motion of the solvent.

  Figure 10.42 reports two spectral trends recorded at 612 nm (graphs a and c), and in two

  independent experiments (labeled as 1 and 2, respectively).

  1.2

  A

  0.6

  hν

  350 400 450 500 550 600 650 700 750

  λ (nm)

  FIGURE 10.41 Spectral evolution of the photochromic SpO upon UV irradiation.

  The Emergence of Chaos in Time

  375

  1

  0.50

  0.54

  1

  A

  A

  0.45

  0.25

  0.36

  0.00 0 500 1000 1500 2000 2500 3000 3500

  1800

  2000

  2200

  (a)

  t (sec)

  (b)

  t (sec)

  0.6

  2

  0.50

  2

  0.5

  A

  A

  0.25

  0.4

  0.3

  0.00 0 500 1000 1500 2000 2500 3000 3500

  1800

  2000

  2200

  (c)

  t (sec)

  (d)

  t (sec)

  FIGURE 10.42 Spectral profiles recorded at 612 nm and generated by the “Hydrodynamic Photochemical

  Oscillator” based on the photochromic SpO in two distinct experiments, labeled as 1 (graph a) and 2 (graph c).

  Graphs b and d show two enlargements of the kinetics 1 and 2, respectively.

  Although the experimental conditions were very similar (see the data in Table 10.2, where

  the subscripts i and f refer to the initial and final states, respectively), the two profiles of A

  versus time are significantly different. It is worthwhile noticing that the oscillations shown in

  Figure 10.42 are recordable also at wavelengths where both SpO and MC do not absorb, for

  example at 800 nm, confirming that are due to the hydrodynamic motions of the solutions.

  The discrepancy between the two kinetics (1 and 2) is further proof of how convection is

  sensitive to the initial conditions. In both cases, we have oscillations in the signals of A ver-

  sus time, but they are not the same. The Fourier Transforms (see Figure 10.43) demonstrate

  that in both cases we have a discrete number of frequencies. However, in experiment 1,

  TABLE 10.2

  Contour Conditions Relative to the Experiments

  1 and 2 Shown in Figure 10.42.

  Conditions

  Exp. 1

  Exp. 2

  h

  3.1

  3.1

  i

  h

  3.0

  3.0

  f

  Ti

  25.3°C

  25.0°C

  Tf

  25.4°C

  25.2°C

  P

  967.0 hPa

  967.7 hPa

  i

  P

  966.2 hPa

  967.0 hPa

  f

  (Humidity)i

  43%

  42.6%

  (Humidity)f

  41.4%

  43.7%

  376

  Untangling Complex Systems

  1

  0.02

  Amplitude

  0.000.00

  0.03

  0.06

  0.09

  0.12

  0.15

  Frequency (Hz)

  2

  0.02

  Amplitude

  0.000.00

  0.03

  0.06

  0.09

  0.12

  0.15

  Frequency (Hz)

  FIGURE 10.43 Fourier spectra for the spectrophotometric kinetics 1 (graph on top) and 2 (graph at the

  bottom), respectively.

  there is a dominant frequency of 0.0678 s−1, whereas, in experiment 2, more than one fre-

  quency has similar amplitudes. For instance, the frequencies of 0.0584 s−1 and 0.0663 s−1.

  It is reasonable to assume that in both cases Ra

  . By using the values of

  c,1 < ( Ra)1or2 < Rac,2

  the physical parameters for acetone, we deduce that the vertical thermal gradients in the two

  runs are in the range 0 0017

  .

  K < ( T

  ∆ ) ≤ ( T

  ∆ ) < 0 0201

  .

  K. In both experiments, the volume

  1

  2

  that evaporated was 0.1 cm3 after 3500 s. The power absorbed by the solutions was 0.012 J s−1.

  Figure 10.44 shows the hydrodynamic waves spreading MC throughout the solution.

  10.15. The data “b1.txt” are plotted in Figure 10.45. The upper graph shows the heart rate, whereas the lower graph reports the trend of chest volume over time. Both the time series

  refer to a patient exhibiting sleep apnea, namely a sleep disorder characterized by pauses

  in breathing or periods of shallow breathing. The anomalous breathing periods can last

  for a few seconds to several minutes.

  Before running a routine of TISEAN, you can be acquainted with the necessary inputs

  and the right syntax, by typing > name_of_routine -h.

  In Figure 10.46, you can see the outputs of the calculations. The graphs in the left col-

  umn of the Figure refer to the heart rate time series, whereas the charts in the right column

  Time

  FIGURE 10.44 Sequence of snapshots showing hydrodynamic convective waves spreading MC throughout

  the solution.

  The Emergence of Chaos in Time

  377

  100

  ts/min)

  (bea 80

  t rate ar 60

  He

  0

  2000

  4000

  6000

  8000

  t (s)

  30000

  .u.)

  0

  Chest volume (a −30000

  0

  2000

  4000

  6000

  8000

  t (s)

  FIGURE 10.45 Time series of heart rate (top graph) and chest volume (lower graph) for a patient showing

  sleep apnea.

  2.1

  1.5

  1.4

  1.0

  al information 0.7

  al information 0.5

  tu

  tu

  Mu

  Mu 0.0

  0

  5

  10

  15

  20

  0

  5

  10

  15

  20

  (a)

  τ

  (b)

  τ

  ors 1.0

  ors 1.0

  0.8

  0.8

  0.6

  0.6

  0.4

  0.4

  0.2

  0.2

  0.0

  0.0

  2

  Fraction of false neighb

  4

  6

  8

  10

  Fraction of false neighb

  2

  4

  6

  8 10 12 14 16 18 20

  (c)

  m

  (d)

  m

  −2

  −2

  D

  D −4

  −4

  −6

  0

  10

  20

  30

  40

  50

  0

  10

  20

  30

  40

  50

  (e)

  Δt

  (f)

  Δt

  FIGURE 10.46 Determination of the time delays (a and b), embedding dimensions (c and d), and Lyapunov

  exponents (e and f) for the heart rate and chest volume time series, respectively.

  378

  Untangling Complex Systems

  refer to the chest volume time series. The plots of the first row regard the determination

  of the time delay ( τ) through the calculation of mutual information (routine mutual).

  It results that the first minimum in (a) is for τ = 6, whereas in (b‖δ(t)‖) is for τ = 2. The

  plots of the second row regard the calculations of the fraction of the false nearest neigh-

  bors (routine false_nearest). The fraction is 0 for m = 8 in (c) and m = 15 in (d). Therefore, by using the Takens’ theorem, it results that the phase space for the heart rate time series

  has τ = 6 as time delay and m = 8 as embedding dimension, whereas that for the chest

  volume time series has τ = 2 and m = 15. The largest Lyapunov exponent calculated by

  the Kantz’s method (routine lyap_k) for heart rate is λ = 0.011 (graph (e)), whereas that for

  the chest volume is λ = 0.033 (graph (f)), indicating the possibility that both time series

  are chaotic.

  Chaos in Space

  11 The Fractals

  A fractal is a way of seeing infinity

  Benoit Mandelbrot (1924–2010 AD)

  11.1 INTRODUCTION

  In Chapter 10, we have learned that chaotic dynamics can originate “strange” structures. An exam-

  ple is the bifurcation diagram of the logistic map (see Figure 10.9). You probably remember that it describes the evolution of the relative abundance x of a population as a function of its growth rate r.

  n

  If we zoom in on specific regions of the bifurcation diagram, where “white patches” are interspersed

  with clouds of infinite points, copies of the overall diagram reappear at different spatial scales. The

  bifurcation diagram is self-similar whatever is the magnification scale. 1

  Even the Lorenz model for weather forecasts originated a “strange” attractor in the chaotic

  regime (see Figure 10.15). At first sight, the Lorenz attractor looks like a butterfly: it consists of a pair of surfaces, as if it were a pair of wings, merging into the central part—the body of the grace-ful flying insect. If we look at the details of the attractor, we find, just as Lorenz realized, every

  chaotic trajectory crosses an infinite number of surfaces and not just two. To gain more insight

  into the geometrical structure of the Lorenz’s strange attractor, it is useful to exploit the strategy

  contrived by Poincaré while he was studying the three-body problem mentioned in Chapter 10.

  Poincaré discovered that the complexity of the analysis of a swirling trajectory can be reduced by

  focusing on its intersections with a fixed surface. Such a surface, now known as Poincaré section,

  transforms a continuous N-dimensional trajectory into an ( N−1)-dimensional map if the surface

  is transverse to the trajectory (see Figure 11.1). The resulting ( N−1)-dimensional map is called Poincaré map.

  In particular, the Poincaré map of the Lorenz attractor for z = 27 looks like bundles of sequences

  of points (Viswanath 2004). Every bundle of points is self-similar because it maintains its regular

  spacing at different levels of magnification (in principle, ad infinitum).

  In 1976, the theoretical astronomer, Michel Hénon, after being acquainted with the Lorenz

  attractor, formulated a two-dimensional map as a simple model having the essential properties of

  the Lorenz system (Hénon 1976). The Hénon map is given by

  x

  2

  1

  −

  +

  n+ = yn

  axn 1 [11.1]

  yn+1 = bxn [11.2]

  where a and b are two adjustable parameters. When a = 1.4 and b = 0.3, the Hénon map gives rise to a strange attractor, looking like a boomerang and shown in Figure 11.2.

  Successive enlargements of the exterior border of the boomerang-like shape reveal the fine

  structure of the attractor. In the first picture, the border consists of three lines. By zooming into the

  1 The only limit that exists is imposed by the degree of accuracy of our calculations. In other words, the limit depends on the number of significant figures we used in building the bifurcation diagram of the logistic map.

  379

  380

  Untangling Complex Systems

  rk+2

  rk+1

  rk

  FIGURE 11.1 Representation of a Poincaré section that transforms a continuous three-dimensional trajec-

  tory into a bi-dimensional map.

  0.4

  Hénon attractor

  0.195

  Z1

  0.3

  0.19

  0.2

  Z1

  0.185

  0.1

  0.18

  Z2

  y

  0

  0.175

  0.17

  −0.1

  0.165

  −0.2

  0.16

  −0.3

  0.155

  −0.4−1.5

  −1

  −0.5

  0

  0.5

  1

  1.5

  0.62 0.64 0.66 0.68 0.7 0.72 0.74 0.76 0.78 0.8 0.82

  0.1778

  Z3

  0.181

  Z2

  0.18

  0.1776

  0.179

  0.1774

  0.178

  Z3

  0.1772

  y

  yy 0.177

  0.177

  0.176

  0.1768

  0.175

  0.174

  0.1766

  0.173

  0.1764

  0.704 0.705 0.706 0.707 0.708 0.709 0.71 0.711 0.712 0.713 0.714

  0.685 0.69 0.695 0.7 0.705 0.71 0.715 0.72 0.725 0.73 0.735

  x

  x

  FIGURE 11.2 A series of three enlargements (Z1, Z2, and Z3) into a portion of the exterior border of the

  Hénon attractor.

  rectangle Z1 of Figure 11.2, we see that there are six lines: a single curve, then two closely spaced curves above it, and then three more. An enlargement in Z2 reveals that the three lines are actually

  six curves; grouped one, two, three, precisely as in Z1. A further expansion of the last three lines

  unveils the structure also observed in Z1; i.e., one, two and three lines. And so on. Self-similarity

  can continue indefinitely. The limit is imposed only by the number of decimal figures we use in

  our calculations.

  Chaos in Space

  381

  TRY EXERCISE 11.1

  Self-similarity can be encountered in every strange attractor. In fact, the strange attractors are

  examples of FRACTALS.

  11.2 WHAT IS A FRACTAL?

  A fractal is a complex geometric shape. It maintains its sophisticated form, or the main features of

  its complex structure, under different levels of magnification, i.e., under changes of spatial scale.

  This peculiarity of fractals is defined as either “scale invariance” or “scale symmetry,” or more

  often, “self-similarity.” Several fractals can be built by following simple rules. A fractal that often

  appears in the strange attractors generated by chaotic dissipative dynamics is the Cantor set. For

  example, it is the fractal that can be detected in the Lorenz attractor. The set is named after the

  nineteenth-century mathematician Georg Cantor. However, it was created by Henry Smith, who

  was a nineteenth-century geometry professor at the Oxford University. 2 To build a Cantor set, we start with a bounded interval C . We remove an open interval from inside . is divided into two

  0

  C 0 C 0

  subintervals, each containing more than one point. Iteratively, we remove an open interval from

  each remaining interval. In this way, the length of the remaining intervals at each step shrinks to

  zero as the construction of the set proceeds. After an infinite number of iterations, we obtain the

  Cantor set. The most often mentioned Cantor set is that obtained by removing the middle third of

  every interval (see Figure 11.3). In the end, it consists of an infinite number of infinitesimal pieces, separated by gaps of various lengths, and having a negligible length.3 Of course, it is impossible to print a fractal on a piece of paper.

  TRY EXERCISE 11.2

  Another well-known and perfectly self-similar fractal is the Koch curve, contrived by the Swedish

  mathematician Helge von Koch. For its construction, we start with a horizontal segment ( K ). Then,

  0

  we delete the middle third of K , and we replace it with the other two sides of an equilateral triangle,

  0

  and we obtain K (see Figure 11.4). In the subsequent stages, we repeat recursively the same rule: 1

  C 0

  C 1

  C 2

  C 3

  C 4

  FIGURE 11.3 Scheme showing the first four steps for constructing the Cantor set by removing the middle

  third of every interval. It has been obtained by using the “Examples of Fractals” model, Complexity Explorer

  project, http://complexityexplorer.org.

  2 The first self-similar fractals were invented earlier than the discovery of strange attractors. In the beginning, they were merely “pathological phenomena” interesting only mathematicians.

  3 Cross sections of strange attractors are often Cantor set devoid of exact self-similarity. However, they are topological Cantor sets. A topological Cantor set C has two properties. First, C contains only single points and no intervals. Second, every point in C has a neighbor arbitrarily close by. A famous example of topological Cantor set is the logistic map

 

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